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ArticlePeer ReviewedOpen AccessPlagiarism Passed
Paper ID:IJSREM67045

A DUAL-PATHWAY APPROACH FOR ECO-FRIENDLY RECOVERY OF SILVER FROM DDRM E-WASTE USING ORGANIC LEACHING AGENTS

Stream/Area:

-

Subject:

-

Paper ID:

IJSREM67045

Volume:

10 |

8 |

Aug 2026

Pages:

1-6

Publication Frequency:

Monthly (12 issues per year)

DOI
Digital Object Identifier
10.55041/IJSREM67045

License:International Journal of Scientific Research in Engineering and Management follows the Creative Commons Attribution 4.0 (CC BY 4.0) License, allowing free use and distribution with proper attribution.

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Authors

Ram Prasath Ramasamy

Ram Prasath Ramasamy

Department of Environmental Engineering

Government College of Technology,Coimbatore

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Mohanadhas Chandrika Ravathi

Department of Environmental Engineering

Government College of Technology,Coimbatore

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Abstract

Electronic waste (e-waste) contains significant quantities of valuable metals that can be recovered through environmentally sustainable processes. This study investigates an eco-friendly dual-pathway approach for the recovery of silver from discarded Double Data Rate Random Access Memory (DDRM) modules using organic acid leaching followed by electrolysis. Waste DDRM samples were collected, shredded and subjected to alkaline pretreatment using different concentrations of potassium hydroxide (KOH) to remove the epoxy coating. Sonication was subsequently employed to enhance the removal of the protective polymer layer. The pretreated DDRM was then subjected to leaching using citric acid and formic acid in the presence of hydrogen peroxide as an oxidizing agent. The leachates were analyzed using UV–VIS spectroscopy to confirm the presence of silver ions, while electrolysis was employed to recover the dissolved metal. FTIR analysis confirmed the breakdown of epoxy functional groups after alkaline pretreatment. Among the organic acids investigated, citric acid exhibited better silver leaching performance than formic acid. The study demonstrates that organic acid leaching combined with electrolysis provides a simple, economical and environmentally safer alternative for silver recovery from DDRM e-waste.

KEYWORDS

DDRM e-waste silver recovery organic acid leaching citric acid formic acid electrolysis.

Cite This Article

Ram Prasath Ramasamy, Mohanadhas Chandrika Ravathi, "A DUAL-PATHWAY APPROACH FOR ECO-FRIENDLY RECOVERY OF SILVER FROM DDRM E-WASTE USING ORGANIC LEACHING AGENTS," International Journal of Scientific Research in Engineering and Management, vol. 10, no. 8, pp. 1-6, Aug 2026. https://doi.org/10.55041/IJSREM67045

Full Article/Conclusion

The present study demonstrated the feasibility of recovering silver from DDRM e-waste through an eco-friendly dual-pathway process involving alkaline pretreatment, organic acid leaching and electrolysis. KOH pretreatment showed better epoxy removal. FTIR confirmed the chemical breakdown of the epoxy layer, while UV–VIS analysis verified the presence of silver ions in the leachate. Among the two organic acids, citric acid demonstrated better leaching and recovery performance than formic acid, with the reported recovery range of 65–90% compared with 45–80% for formic acid. The proposed process provides a simple and comparatively environmentally safer route for recovering valuable metals from DDRM e-waste.

References

[1]  Gautam Mishra, Rohit Jha, Mudila Dhanunjaya Rao, Arunabh Meshram (2021). Recovery of silver from waste printed circuit boards (WPCBs) through hydrometallurgical route: A review. Environmental Challenges, 2021 – Elsevier. [2]   Abdel Mohsen Onsy Mohamed (2024). Sustainable recovery of silver nanoparticles from electronic waste: applications and safety concerns. Academia Engineering, 2024. [3]  J. Cui, H.J. Roven (2011). Electronic Waste. Waste: A Handbook for Management, Chapter 20, pp. 281–296. [4]   A. Chauhan, R. Bal, R. Srivastava (2025). Upcycling Waste Electronic Chips into Metallic Catalysts for Sustainable Biomass Valorization into Fuel Additives and Fine Chemicals. Industrial & Engineering Chemistry Research. [5]  Massimiliana Pietrantonio, Stefano Pucciarmati, Federica Forte (2025). Recovery of metallic gold, silver and copper from end-of-life mobile phones by hydrometallurgy. Journal of Materials. [6]  DS Ferreira, ER Pereira-Filho (2025). A preliminary study of a sequential leaching process to recover Ag, Au, Cu, and Sn from E-waste. Hydrometallurgy. [7]   S. Diallo, LH Tran, D. Larivière, JF Blais (2025). Leaching and recovery of rare earth elements, copper, nickel, silver and gold from used smartphone circuit boards. Minerals Engineering. [8]    A. Trivedi, M. Khetri, A. Surampudi, MC Gupta (2025). Gold Metal Recovery from Electronic Waste through Laser Generation of Micro and Nanoparticles. ACS Omega. [9]   O. Gajare, NB Jadhav, S. Zele, N. Lucas (2025). Sustainable silver recovery by chemical treatment of metal rich fines from solar panel waste. Solar Energy Materials. [10]   DA Ferreira-Filipe, AC Duarte, AS Hursthouse (2025). Biobased Strategies for E-Waste Metal Recovery: A Critical Overview of Recent Advances. Environments.

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Publication Date

8/31/2026

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Double-Blind Peer Review

Review Rounds: 2

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